Today is my final post covering the U.S. Environmental Protection Agency’s (EPA) December 16, 2016 report: “Hydraulic Fracturing for Oil and Gas: Impacts from the Hydraulic Fracturing Water Cycle on Drinking Water Resources in the U.S.” I reviewed EPA’s analysis of the potential for drinking water contamination during the oil and gas industry’s management of produced water. EPA includes within the definition of produced water both the fluid which has been injected down a well to hydraulically fracture oil and gas rock formations and the normally salty water contained within the rock formation itself. Once rocks are fractured and the pressure is released on a well undergoing hydraulic fracturing, part of the hydraulic fracturing fluid and some of the salty formation water flow back up the well to the surface. The management of the produced water once it reaches the surface is important to safeguarding drinking water resources.
Spills are probably the number one problem with waste handling in most industries, so it is not surprising that there are multiple ways produced water is spilled at oil and gas wells being drilled or hydraulically fractured. We are all too familiar with the blowout and spill which occurred in the Gulf of Mexico in 2010. Who did not see the underwater videos of oil and brine pouring out of the well on the sea floor? After all it went on for 5 months. Blowouts occur on-shore as well. When they occur at a well being fractured, it can result in oil and gas, formation water, and hydraulic fracturing fluid all coming back up the well and being released at the ground surface. If the well casing is damaged during the blowout then there is also the potential of produced water being released into rock formations with groundwater aquifers. Fortunately blowouts are very rare. When blowouts occur on-shore, it is easier to stop the flow and to clean-up the mess. Just as problematic, though not as spectacular, are the spills of produced water from day to day management activities.
When oil and gas wells are new, they produce more water. Horizontal wells produce more water than vertical wells. More hydraulic fracturing chemicals will be in the produced water during the early life of a well. Over time the produced water will be composed predominantly of the salty formation water from the oil and gas formation. Unfortunately the formation water is not benign. It is brine and full of chlorine, bromine, metals, organic oil and gas constituents, and naturally occurring radioactive minerals. There is a lot of this produced water coming up from active oil and gas wells all over the United States, whether they have been hydraulically fractured or not. EPA estimates horizontal wells produce 1100 gallons of produced water per day and vertical wells about 500 gallons a day. But the exact volume depends on the actual formation being fractured. The rock formation also determines what the composition of the produced water will be. For example in the Marcellus Shale, the produced water contains more barium and strontium. But even within a single rock formation like the Marcellus, the composition can vary widely. EPA has documented salinities of between 1500 and 300,000 milligrams per liter in the Marcellus Shale. The produced water characteristics of hydraulically fractured wells are not substantially different from produced waters out of wells which have not been hydraulically fractured. The main difference between the two types of water would be the chemicals used in hydraulic fracturing; chemicals like ethylene glycol, propylene glycols, toluene, xylene, 2-butanone, acetone and many others. Chemical additives are a small amount of the total fluid used for hydraulic fracturing, on average less than 1 percent. Most of the fluid used to fracture a well is simply water.
When the produced water reaches the surface, it must be managed. Either it is collected in tanks or discharged into pits. Thank goodness state governments have ended the practice of allowing discharge into unlined pits. According to EPA, unlined pits have been the source of contamination to water in a number of cases in New Mexico, southwest Pennsylvania and possibly in Texas. But lined pits can leak too if the liner isn’t installed adequately. Produced water is often piped to pits or storage. There have been a number of incidents where pipelines have broken or valves have been accidentally left open. In 2015, North Dakota had one of the largest pipeline spills of produced water. About 2.9 million gallons of produced water were released.
Of course pipelines sometimes leak. So does other equipment the produced water passes through, such as hoses. Even storage containers leak. The best data that EPA was able to come up with in examining the various sources of spills was from North Dakota. There were 552 leaks or spills between 2012 and 2013. EPA says that was somewhere between 5 – 7 releases of produced water per 100 active production wells. Most of the produced water spills were the result of equipment leaks and overflows of tanks. This seems like a lot of spills to me. Of course not every spill was a big one; they ranged from 170 gallons to 74,000 gallons.
Pits and storage containers are not the final resting place for produced water. With the amount of water being produced over the lifetime of an oil and gas well, the water has to be permanently disposed of somewhere. Most states have lots of disposal injection wells permitted under the Underground Injection Control regulations. So in the majority of oil and gas producing states, the produced water is piped or trucked to an injection well for disposal. Injection wells are installed into permeable rock formations at great depths and are specifically designed for final disposal of liquid waste. EPA says in 2012, there were 26,400 disposal injection wells and 65 % of them were located in Texas, Oklahoma and Kansas. EPA cites a study that estimates 93 % of all produced water in the U.S. is injected into disposal wells.
Interestingly enough Pennsylvania only has 9 permitted underground injection wells in the whole state. Trucking produced water to another state where there is a disposal well is pretty expensive, except in southwest Pennsylvania. At one time produced water in Pennsylvania was being sent to Publically Owned Treatment Works (POTWs). These facilities treat municipal waste. Produced water was also being shipped to commercial facilities called Centralized Waste Treatment (CWT). This is no longer allowed in Pennsylvania because neither POTWs nor CWTs were able to treat the produced water from the Marcellus adequately and it was causing problems for downstream drinking water suppliers. Today over 80 % of produced water in Pennsylvania is being treated and reused as water to hydraulically fracture oil and gas wells.
In the 10 years it has taken EPA to write their report on the impact of hydraulic fracturing on drinking water resources, a lot of improvements have been made in management of produced water which consequently has reduced potential impact on drinking water. It looks like more improvements could certainly be made in produced water management. Many of the produced water spills are caused by human error or equipment failure. EPA was unable to quantify the number of spills of produced water nationally or the affects on drinking water sources. However, they did examine a few states which keep spill records. EPA found that of 575 produced water spills in California between 2009 and 2014, 18 percent impacted surface water. Quality improvement in produced water handling could reduce the number of spills and impacts on drinking water resources.
